Difference between revisions of "Electro-optic cofficient"

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The electro-optic coefficient is a measure of the changability optical activity of a material when an electric field is applied.
r<sub>33</sub> (pronounced "r three three") also called the electro-optic coefficient is a measure of the changability optical activity of a material when an electric field is applied.


<math>r_{33} = \beta(\epsilon,\omega)N<cos^3\theta>\,\!</math>  
<math>r_{33} = \beta(\epsilon,\omega)N<cos^3\theta>\,\!</math>  
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where
where


<math>\beta(\epsilon,\omega)\,\!</math> is the [[molecular first polarizability]] which at a give wavelenth &omega;  
<math>\beta(\epsilon,\omega)\,\!</math> is the [[molecular first hyperpolarizability]] which at a give wavelenth &omega;  


<math>N<cos^3\theta>\,\!</math>  is  number density
<math>N\,\!</math>  is chromophore number density
 
<math><cos^3\theta>\,\!</math>  is  the acentricity or order parameter
 
 
=== Figure-of-Merit ===
 
Figure-of-merit: r33 preferably > 1000 pm/V
 
Current Status: 600pm/V
 
For poled polymers for THz generation and detection
 
Figure-of-merit: r33 preferably > 350 pm/V
 
Current Status: 600pm/V
 
 
=== Measurement ===
[[Teng-Mann Method]]
 
[[Attenuated Total Reflectance]]

Latest revision as of 09:21, 8 November 2011

r33 (pronounced "r three three") also called the electro-optic coefficient is a measure of the changability optical activity of a material when an electric field is applied.

<math>r_{33} = \beta(\epsilon,\omega)N<cos^3\theta>\,\!</math>

where

<math>\beta(\epsilon,\omega)\,\!</math> is the molecular first hyperpolarizability which at a give wavelenth ω

<math>N\,\!</math> is chromophore number density

<math><cos^3\theta>\,\!</math> is the acentricity or order parameter


Figure-of-Merit

Figure-of-merit: r33 preferably > 1000 pm/V

Current Status: 600pm/V

For poled polymers for THz generation and detection

Figure-of-merit: r33 preferably > 350 pm/V

Current Status: 600pm/V


Measurement

Teng-Mann Method

Attenuated Total Reflectance