Difference between revisions of "Electronic Coupling Between Orbitals"
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[[Image:Beta-adjacent.png|thumb|300px|]] | |||
We will discuss the electronic structure of π-conjugated organic molecules at various levels of complexity. π-conjugated molecules have a sigma electron framework and π electron framework. | |||
Here we start at the simplest level that is basically derived from a Hückel Molecular Orbital approach in order to understand conjugated systems. | |||
In this model, orbitals that are on atoms that are directly π-bonded to one another and whose p-orbitals are in a plane can interact. This interaction is called the electronic coupling between the orbitals which has units of energy. | |||
In the Hückel approximation this energy is the same for all carbon p-orbitals that are adjacent to on another and is called Β. | |||
[[Image:Beta-nonadjacent.png|thumb|300px|]] | |||
Revision as of 11:44, 19 May 2009
Return to Molecular Orbitals Menu | Next Topic
We will discuss the electronic structure of π-conjugated organic molecules at various levels of complexity. π-conjugated molecules have a sigma electron framework and π electron framework.
Here we start at the simplest level that is basically derived from a Hückel Molecular Orbital approach in order to understand conjugated systems.
In this model, orbitals that are on atoms that are directly π-bonded to one another and whose p-orbitals are in a plane can interact. This interaction is called the electronic coupling between the orbitals which has units of energy. In the Hückel approximation this energy is the same for all carbon p-orbitals that are adjacent to on another and is called Β.
