Cuprous Oxide Solar Cell

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K-12 Outreach Kits and Labs

Overview

When copper metal is oxidized it can take several oxidation states.

Cupric oxide with a copper(II) oxidation state is black: 2 Cu + O2 → 2 CuO

cuprous oxide is with the copper(I) oxidation state is red.

4 Cu + O2 → 2 Cu2O.

Cuprous oxide is a semiconductor. It has a bandgap between it ground state and its conduction band. Without light some electrons are able to jump the band and it acts as a battery. With light the cuprous oxide jumps to the conduction band and increased electricity flows. In this design the charge moves through a gelatin electroylte and to a non oxidized collection electrode. Using a gelatin electrolyte is less messy that a purely liquid electrolyte. A solid clear conductor is not great for this application because it can not make uniform contact with the copper surface.


Materials

  • Copper foil (snail tape) from the gardening store
  • Wires and solder
  • Clear rigid plastic sheet (old cd case, or plastic lid from salad container.)
  • clear plastic packing tape
  • clear gelatin
  • table salt
  • volt meter


Construction

Links