Hyper Rayleigh Scattering

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Hyper Rayleigh Scattering (aka Harmonic Light Scattering) is one method for measuring β.

Overview

The Hyper Rayleigh Scattering - Test best schematic

An incident laser generates a second harmonic signal, specifically the frequency double signal. This can be related to the beta of the sample using this formula:

<math>\frac {I_{sample}} {I_{solvent}} = \frac {N_{sample} \langle \beta^2 _{sample} \rangle + N_{solvent} \langle \beta^2_{solvent}\rangle} {N_{solvent} \langle \beta^2_{solvent}\rangle}\,\!</math>
HRS spectrum for 1.5 μm TCP1 in CHCl3

See Firestone 2004 [1].


See Wikipedia on Rayleigh Scattering

See also Density Functional Theory

Technique

Video to come

Significance

References

  1. K. A. Firestone, P. Reid, R. Lawson, S. H. Jang, and L. R. Dalton, “Advances in Organic Electro-Optic Materials and Processing,” Inorg. Chem. Acta, 357, 3957-66 (2004)