Materials Processing and Fabrication

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A great amount of research effort is devoted to developing new ways to apply materials to substrates in extremely thin organized layers so as to improve performance and to make the large scale manufacturing of devices economical. Some techniques that are practical for developing a single device with record breaking efficiency would not work for making millions of devices in a production line. Also engineers must be concerned with the durability of devices under real world conditions of heat, moisture and oxygen. At the same time new nanotechniques and self assembly make it possible to build novel structures virtually one molecule at a time.


Deposition

Spin Casting

Self Assembly

Crystal growth

Layer by layer deposition

Poling

Optically assisted poling

Electric Field poling

Patterning

Nanoimprinting

Soft Lithography

Thermomechanical nanolithography

Etching

Polymer waveguide fab: RIE

Reactive Ion Etching of a polymer with applied mask

Reactive Ion Etching (RIE) is used to convert a slab waveguide into a channel waveguide.

  1. First a slab is prepared with a core layer (higher index of refraction) is placed on a polymer undercladding on a silicon substrate.
  2. A metallic photo mask is applied to protect the core material.
  3. A plasma of oxygen is used to eat away the unmasked portion of the polymer.
  4. The metalic mask is removed and the ribbon of core material is fully encased with overcladding.

Sol-gel waveguide fabrication

Sol-gel waveguide fabrication (including gray scale masking)

This technique builds a complex sol-gel waveguide using completely wet techniques (no vacuum required). Direct illumination by UV through a mask is able to fix portions of the core in place, while unfixed portions are washed away. A series of steps like this can be used to build a complex device.

Polymer waveguide fab: Results

Etched polymer waveguide

The company Photon X has commercialized the polymer waveguide process. The SEM (5micron line shown) shows very smooth sidewalls from a high quality etching process. Walls can only have roughness of 40-50 nm before there is significant optical loss. The polymer waveguide shows excellent light transmission through a 4 mum x 4 mum waveguide core that has been designed to couple very well with an optical fiber.

See Yeniay [1]

Polymer waveguide fab UV curing

Two waveguides produced by UV photo curing process

This waveguide is created using the same UV curing process that is used with sol-gels. This shows two waveguides very close to each other. The channel is very difficult to control using photo etching process. The SEM shows a little cross striation but overall very good quality results.

See Viens 1999 [2]

Polymer athermal Array Waveguide Gradiant AWG filter

Measured fiber-to-fiber transmission spectra

An array waveguide gradiant is used to separate out wavelengths into separate ports. To characterize the device you shine a variety of wavelengths through the device simulating various information carriers and then measure the output from each port. The fluorinated polymer device was able to achieve these results:

  • Insertion loss: 3 dB
  • Adjacent crosstalk: -30dB
  • Non-adjacent crosstalk: -28 dB

This passive polymer technology is being used to connect servers (interconnects) in server forms over very short distances with tremendous data rates.


Temperature dependence.png

An athermal device performs equally well at different temperatures without temperature control.

Wavelength Temperature Dependence dλ/dt :

  • without superstrate: 12pm/ °C
  • with superstrate: - 0.5pm/ °C

See Gao 2002 [3]





References

  1. Yeniay, et. al. J. Lightwave Tech. 22, 154
  2. Viens, et. al. Proc. SPIE (1999)
  3. Gao, et. al. European Conference on Optical Comm.2002
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