Nanocrystalline - Dye Solar Cell Lab

K-12 Outreach Kits and Labs

This page is devoted to the research and development of a organic solar cell that can be built in a high school chemistry lab. It is adapted from the nanocrystalline solar cell kit from ICE.

Background

This dye sensitized solar cell, also known as a Graetzel cell uses a thin film of titanium dioxide which has been ground to to a fine powder (nanocrystalline) to increase its reactive surface area. The TiO₂ is sandwiched between two glass slides that coated with conductive and transparent indium tin oxide (ITO). The TiO₂ is impregnated with some kind of colored dye, in this case anthocyanin from raspberry juice, which is the chemical which first traps the solar energy and passes the charge to the TiO₂. Finally the space between the slides is filled with an liquid electrolyte solution of potassium iodide which forms an serves to transport charge (by way of a redox reaction) from the bottom electrode to the dye to complete the circuit.

Light hits the dye which frees an electron to be accepted by the TiO₂, electrons are returned to the dye by a redox reaction in the potassium iodide solution in contact with the rear electrode.

see wikipedia Dye Sensitized solar cells

Procedure

<embed_document width="55%" height="400">http://depts.washington.edu/cmditr/media/Materials_List.pdf</embed_document>

<embed_document width="55%" height="400">http://depts.washington.edu/cmditr/media/Safety.pdf</embed_document>

<embed_document width="55%" height="400">http://depts.washington.edu/cmditr/media/Color_lab_manual.pdf</embed_document>

Download lab manual

Source for materials

Institute for Chemical Education - Nanocyrstaline Solar Cell Kit

Web Links

Alternative Device Instructions

Wisconsin Mrsec TiO2 Example

Student project powerpoint

Solar cell lesson plan

Exploratorium version

Solideas version

New Mexico lesson plans

More high school lesson plans

Instructables version